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1.31 - Precursor Chemistry – Group 13 Nitrides and Phosphides (Al, Ga, and In)
Book chapter

1.31 - Precursor Chemistry – Group 13 Nitrides and Phosphides (Al, Ga, and In)

E.G Gillan
Comprehensive Inorganic Chemistry II, pp.969-1000
Elsevier Ltd, Second Edition
2013
DOI: 10.1016/B978-0-08-097774-4.00132-7

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Abstract

This chapter describes recent developments in the design and use of dual-source and single-source precursors for the growth of group 13 (mainly Al, Ga, and In) nitrides and phosphides. These main-group materials are semiconductors with bandgap energies ranging from the infrared to ultraviolet range and several have well-established uses in visible light emission related to lasers and light-emitting diodes. Many recent precursor-based syntheses target thin film or nanostructured materials growth. Precursor methods are well defined for metal phosphide nanoparticle and nanowire growth, while challenges still exist for the corresponding metal nitride nanostructure growth.
Nanoparticles Aluminum phosphide Precursors Metathesis Indium nitride Gallium phosphide Chemical vapor deposition Gallium nitride Indium phosphide Aluminum nitride Thermolysis

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