Book chapter
Chloroiodomethane
Encyclopedia of Reagents for Organic Synthesis
John Wiley & Sons, Ltd
1995
DOI: 10.1002/047084289X.rc110.pub2
Abstract
[ 593‐71‐5 ] CH 2 ClI (MW 176.38) InChI = 1S/CH2ClI/c2‐1‐3/h1H2 InChIKey = PJGJQVRXEUVAFT‐UHFFFAOYSA‐N (chloromethylating agent for organozinc, ‐lithium, ‐phosphorus, and ‐transition metal compounds, and alkenes; can generate N,N ‐dimethylmethyleneiminium iodide (Eschenmoser's salt) by reaction with N,N,N ′, N ′‐tetramethylmethylenediamine ) Alternate Name: CIM. Physical Data: bp 108–109 °C; d 20 4 2.42 g cm −3 ; n 20 D 1.582. Solubility: sol ethers, acetone, polyhalomethanes, and benzene. Form Supplied in: pale yellow oil; commercially available or readily preparable via halogen exchange of dichloromethane with iodide sources. Analysis of Reagent Purity: NMR (CCl 4 /TMS), δ (ppm) 5.00. Handling, Storage, and Precautions: should be stored over tin or silver wire in the dark.
Details
- Title: Subtitle
- Chloroiodomethane
- Creators
- Sotaro Miyano - Tohoku University Sendai JapanGregory K Friestad - University of Iowa Iowa City IA USA
- Resource Type
- Book chapter
- Publication Details
- Encyclopedia of Reagents for Organic Synthesis
- DOI
- 10.1002/047084289X.rc110.pub2
- Publisher
- John Wiley & Sons, Ltd; Chichester, UK
- Number of pages
- 4
- Language
- English
- Date published
- 1995
- Academic Unit
- Chemistry
- Record Identifier
- 9983985929502771
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