Book chapter
Crystal engineering [2+2] photodimerizations via templates and hydrogen bonds: case of styrylthiophenes
Photochemistry, Vol.43, pp.321-330
Royal Society of Chemistry
2015
DOI: 10.1039/9781782622772-00321
Abstract
Crystal engineering strategies have been used to modify solid-state packings to direct [2+2] photodimerizations of olefinic compounds that are photostable as pure solids. The strategies have herein been expanded to achieve rare [2+2] photodimerizations of styrylthiophenes. Two co-crystallization approaches based on hydrogen-bond-driven self-assembly are employed to achieve the photodimerizations that yield regioisomers of a β-substituted thiophene. We expect the co-crystal strategies can be applied to modify solid-state packing as well as achieve photodimerizations of olefins substituted with other unique organic functional groups.
Details
- Title: Subtitle
- Crystal engineering [2+2] photodimerizations via templates and hydrogen bonds: case of styrylthiophenes
- Creators
- Kristin M. HutchinsLeonard R. MacGillivray
- Contributors
- Elisa FasaniAngelo Albini
- Resource Type
- Book chapter
- Publication Details
- Photochemistry, Vol.43, pp.321-330
- Publisher
- Royal Society of Chemistry; Cambridge
- DOI
- 10.1039/9781782622772-00321
- Date published
- 2015
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984230630302771
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