Book chapter
Crystalline and Amorphous Forms of Tungsten Tetrachloride
Inorganic Syntheses: Volume 36, pp.30-34
John Wiley & Sons, Inc
05/02/2014
DOI: 10.1002/9781118744994.ch06
Abstract
Tungsten tetrachloride is the most synthetically useful binary tungsten chloride. This chapter reports on the convenient preparations of WCl 4 from WCl 6 in a crystalline, edge‐sharing bioctahedral polymer form via solid‐state methods and a reactive amorphous powder form of unknown structure via solution methods. A literature procedure is followed for gravimetric determination of tungsten as WO 3 after treatment with HNO 3 and ignition. The chapter discusses the procedure and properties of obtaining crystalline tungsten tetrachloride by solid‐state reduction, and obtaining amorphous tungsten tetrachloride by solution‐phase reduction.
Details
- Title: Subtitle
- Crystalline and Amorphous Forms of Tungsten Tetrachloride
- Creators
- Yibo Zhou - Department of Chemistry, University of Iowa, Iowa City, IA 52242Vladimir Kolesnichenko - Department of Chemistry, University of Iowa, Iowa City, IA 52242Louis Messerle - Department of Chemistry, University of Iowa, Iowa City, IA 52242Selim Alayoglu - Department of Chemistry, University of Maryland, College Park, MD 20742Bryan Eichhorn - Department of Chemistry, University of Maryland, College Park, MD 20742
- Contributors
- Alfred P Sattelberger (Editor)Gregory S Girolami (Editor)
- Resource Type
- Book chapter
- Publication Details
- Inorganic Syntheses: Volume 36, pp.30-34
- DOI
- 10.1002/9781118744994.ch06
- Publisher
- John Wiley & Sons, Inc; Hoboken, New Jersey
- Number of pages
- 5
- Language
- English
- Date published
- 05/02/2014
- Academic Unit
- Radiology; Chemistry
- Record Identifier
- 9983985999302771
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