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Finite molecular assemblies in the organic solid state: toward engineering properties of solids
Book chapter   Peer reviewed

Finite molecular assemblies in the organic solid state: toward engineering properties of solids

Tamara D Hamilton and Leonard R MacGillivray
Advances in Physical Organic Chemistry, pp.109-152
Elsevier Science & Technology
2005
DOI: 10.1016/S0065-3160(05)40003-9

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Abstract

Assemblies of organic molecules that form finite structures represent targets for crystal engineers that can exhibit properties largely independent of crystal packing. Such finite molecular assemblies can display function, such as host–guest behavior and chemical reactivity. Here, we provide a review of finite molecular assemblies characterized in the organic solid state. The assemblies are classified as being either purely synthetic or functional. Examples from both the areas are presented and discussed.

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