Supramolecular Catalysis via Organic Solids: Templates to Mechanochemistry to Cascades

Shweta P Yelgaonkar; Leonard R MacGillivray

doi:10.1002/9783527832033.ch27

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Book chapter

Supramolecular Catalysis via Organic Solids: Templates to Mechanochemistry to Cascades

Shweta P Yelgaonkar and Leonard R MacGillivray

Supramolecular Catalysis, pp.401-411

Wiley‐VCH GmbH

03/14/2022

DOI: 10.1002/9783527832033.ch27

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Abstract

We describe how small‐molecule ditopic receptors act as catalysts to direct intermolecular [2+2] photodimerizations in the solid state. Examples demonstrate successful applications of mechanochemistry to perform supramolecular catalysis in a solvent‐free environment. The approach relies on the process of cocrystallization of multiple components that lead to functional supramolecular structures. We also show how the method can be extended to molecular and supramolecular cascades.

cocrystallization

mechanochemical‐mediated cascade

mechanochemistry

organocatalysis

solid‐state 2+2 photoreaction

supramolecular catalysis

Details

Title: Subtitle: Supramolecular Catalysis via Organic Solids: Templates to Mechanochemistry to Cascades
Creators: Shweta P Yelgaonkar
Leonard R MacGillivray
Contributors: Piet W.N.M van Leeuwen (Editor)
Matthieu Raynal (Editor)
Resource Type: Book chapter
Publication Details: Supramolecular Catalysis, pp.401-411
DOI: 10.1002/9783527832033.ch27
Publisher: Wiley‐VCH GmbH; Weinheim, Germany
Number of pages: 11
Language: English
Date published: 03/14/2022
Academic Unit: Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
Record Identifier: 9984217549602771

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