Logo image
Dataset for PCB Sulfates in Human Serum from Mothers and Children in Urban and Rural U.S. Communities
Dataset   Open access

Dataset for PCB Sulfates in Human Serum from Mothers and Children in Urban and Rural U.S. Communities

Duo Zhang, Panithi Saktrakulkla, Rachel F Marek, Hans-Joachim Lehmler, Kai Wang, Peter S Thorne, Keri C Hornbuckle and Michael W Duffel
University of Iowa
05/02/2022
DOI: 10.25820/data.006162
txt
1-PCB Sulfates_in_Human_Serum-Readme19.64 kBDownloadView
READMEDescribes files, methods, personnel, and grant funders.Open Data Commons Attribution (ODC-By) V1.0 Open Access
csv
2_PCB_Sulfates_in_East_Chicago_Human_Serum8.97 kBDownloadView
Open Data Commons Attribution (ODC-By) V1.0 Open Access
csv
3_PCB_Sulfates_pgPerSample_in_CJ_Human_Serum41.24 kBDownloadView
Open Data Commons Attribution (ODC-By) V1.0 Open Access
csv
3_PCB_Sulfates_Raw_Mass_CJ_Human_Serum39.85 kBDownloadView
Open Data Commons Attribution (ODC-By) V1.0 Open Access
csv
3_PCB_Sulfates_SSRecoveries_in_CJ_Human_Serum3.39 kBDownloadView
Open Data Commons Attribution (ODC-By) V1.0 Open Access

Abstract

This dataset from the Iowa Superfund Research Program (isrp) includes PCB sulfate concentrations from serum samples collected from individuals living in Columbus Junction (CJ), Iowa (N=24) and East Chicago (EC), Indiana (N=24). PCB sulfates in serum samples were extracted and then enzymatically hydrolyzed to the corresponding OH-PCBs with Helix pomatia sulfatase that had been highly purified by affinity chromatography. The resulting OH-PCBs were converted to their corresponding methoxy-PCB (MeO-PCB) derivatives which were analyzed by GC-MS/MS. Comparison of results of incubations with and without sulfatase-catalyzed hydrolysis yielded the concentration of PCB sulfates in the original sample of serum. The maximum number of PCB sulfate congeners quantitated was limited to the 74 MeO-PCB standards available. The total concentration of these PCB sulfates determined in individuals within the CJ group ranged from 530 to 6700 pg/g of serum, while the total of these PCB sulfates determined in individuals within the EC group ranged from 110 to 8900 pg/g of serum.
Polychlorinated Biphenyl Sulfates Organic Pollutants PCB Metabolism PCB Metabolites in Human Serum Polychlorinated Biphenyls PCBs Analytical Core Synthesis Core ISRP Project 3 2015-2020

Details

Metrics

21 File views/ downloads
856 Record Views
Logo image