Journal article
1,1,2,2-tetrachloroethane reactions with OH-, Cr(II), granular iron, and a copper-iron bimetal: insights from product formation and associated carbon isotope fractionation
Environmental science & technology, Vol.41(11), pp.4111-4117
06/01/2007
DOI: 10.1021/es063040x
PMID: 17612198
Abstract
Despite widespread implementation of zero-valent iron remediation schemes, the manner and order of chemical bond cleavage in iron-mediated organohalide transformations remains imperfectly understood. We present insights from carbon isotope fractionation for the dehalogenation of 1,1,2,2-tetrachloroethane (1,1,2,2-TeCA) and 1,1,1-trichloroethane (1,1,1-TCA) by various reactants. Elimination of HCl by OH- gave isotope fractionation in 1,1,2,2-TeCA of Euro = -25.6 per thousand, KIE(c) = 1.02 to 1.03 per carbon center, consistentwith a concerted (E2) mechanism. In contrast, 1,1,1-TCA reduction by Cr(II), Fe(0), and Cu-plated iron (Cu/Fe) resulted in Euro = -13.6 per thousand to -15.8 per thousand indicating the initial involvement of a single C-Cl bond (KIE(c) approximately 1.03). 1,1,2,2-TeCA reduction by Cr(II), Fe(0), and Cu/Fe yielded Euro = -18.7 per thousand, -19.3 per thousand, and -17.0 per thousand, respectively. In the two latter cases, depletion of the minor product TCE by 26 per thousand indicated its formation via nonreductive dehydrohalogenation. The major 1,1,2,2-TeCA reduction products, cis- and trans-DCE, differed by 2.3 per thousand +/- 1.0 per thousand in Cr(II) systems, but were equivalent in Fe(0) and Cu/Fe systems. In contrast, the ratio of cis-DCE to trans-DCE concentration was 2.5 for reduction with Cr(II) and Fe(0), but -3.8 with Cu/Fe. Complementary isotope and concentration data therefore suggest differences in the transition state geometry and/ or reaction intermediates in each reductant system.
Details
- Title: Subtitle
- 1,1,2,2-tetrachloroethane reactions with OH-, Cr(II), granular iron, and a copper-iron bimetal: insights from product formation and associated carbon isotope fractionation
- Creators
- Martin Elsner - Stable Isotope Laboratory, University of Toronto, 22 Russell Street, Toronto, Ontario M5S 3B1, Canada. martin.elsner@gsf.deDavid M CwiertnyA Lynn RobertsBarbara Sherwood Lollar
- Resource Type
- Journal article
- Publication Details
- Environmental science & technology, Vol.41(11), pp.4111-4117
- Publisher
- United States
- DOI
- 10.1021/es063040x
- PMID
- 17612198
- ISSN
- 0013-936X
- eISSN
- 1520-5851
- Language
- English
- Date published
- 06/01/2007
- Academic Unit
- Center for Health Effects of Environmental Contamination; Civil and Environmental Engineering; Public Policy Center (Archive); Chemical and Biochemical Engineering
- Record Identifier
- 9983991955402771
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