1D and 2D metal–organic frameworks functionalized with free pyridyl groups

Tamara D Hamilton; Dejan-Krešimir Bučar; Manza B.J Atkinson; Giannis S Papaefstathiou; Leonard R MacGillivray

doi:10.1016/j.molstruc.2006.03.099

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1D and 2D metal–organic frameworks functionalized with free pyridyl groups

Journal article

Peer reviewed

1D and 2D metal–organic frameworks functionalized with free pyridyl groups

Tamara D Hamilton, Dejan-Krešimir Bučar, Manza B.J Atkinson, Giannis S Papaefstathiou and Leonard R MacGillivray

Journal of molecular structure, Vol.796(1), pp.58-62

2006

DOI: 10.1016/j.molstruc.2006.03.099

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Abstract

We show that a molecule constructed from an organic solid-state synthesis, namely, rctt-1,3-bis(2-pyridyl)-2,4-bis(4-pyridyl)cyclobutane (ht-2,4′-tpcb) upon reaction with Cu(II) and Zn(II) ions gives one- (1D) and two-dimensional (2D) metal–organic frameworks (MOFs) of composition [Cu(hfac) 2(2,4′-tpcb-ht)] ∞ (where: hfac=hexafluoroacetylacetonate) ( 1) and [ Zn ( 2 , 4 ′ ‐ tpcb ‐ ht ) 2 ( H 2 O ) 2 ] ∞ 2 + ( 2). Each MOF possesses uncoordinated, or free, 2-pyridyl groups that decorate the walls of each extended structure.

[2+2] Photodimerization

Metal–organic framework

Self-assembly

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Details

Title: Subtitle: 1D and 2D metal–organic frameworks functionalized with free pyridyl groups
Creators: Tamara D Hamilton
Dejan-Krešimir Bučar
Manza B.J Atkinson
Giannis S Papaefstathiou
Leonard R MacGillivray
Resource Type: Journal article
Publication Details: Journal of molecular structure, Vol.796(1), pp.58-62
Publisher: Elsevier B.V
DOI: 10.1016/j.molstruc.2006.03.099
ISSN: 0022-2860
eISSN: 1872-8014
Language: English
Date published: 2006
Academic Unit: Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
Record Identifier: 9984216716302771

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