Journal article
[5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinato]iron(II) benzene disolvate
Acta crystallographica. Section C, Crystal structure communications, Vol.60(Pt 2), pp.m57-m59
02/2004
DOI: 10.1107/S0108270103028051
PMID: 14767113
Abstract
The title compound, [Fe(C(44)H(8)F(20)N(4))].2C(6)H(6), contains a four-coordinated Fe(II) atom, which lies on a center of symmetry. The porphyrin macrocycle is planar, and the Fe-N bond distances are in the range 1.9891 (13)-1.9982 (13) A. The spin state of the Fe(II) atom is intermediate (S = 1), as confirmed by NMR spectroscopy. The asymmetric unit contains two half benzene molecules, each lying about an independent inversion centre; one of the benzene rings is located just below (and by inversion symmetry, another is just above) the Fe atom, where it interacts weakly with the porphyrin ring.
Details
- Title: Subtitle
- [5,10,15,20-Tetrakis(pentafluorophenyl)porphyrinato]iron(II) benzene disolvate
- Creators
- Yunghee Oh - Dong-Eui UniversityByoung Chul ShinDale Swenson - University of IowaHarold M Goff - University of IowaSung Kwon Kang - Chungnam National University
- Resource Type
- Journal article
- Publication Details
- Acta crystallographica. Section C, Crystal structure communications, Vol.60(Pt 2), pp.m57-m59
- DOI
- 10.1107/S0108270103028051
- PMID
- 14767113
- ISSN
- 0108-2701
- eISSN
- 1600-5759
- Language
- English
- Date published
- 02/2004
- Academic Unit
- Chemistry
- Record Identifier
- 9984622750102771
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