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A [2+2] cross-photodimerisation of photostable olefins via a three-component cocrystal solid solution
Journal article   Peer reviewed

A [2+2] cross-photodimerisation of photostable olefins via a three-component cocrystal solid solution

Dejan-Krešimir Bučar, Arundhuti Sen, S. V. Santhana Mariappan and Leonard R MacGillivray
Chemical communications (Cambridge, England), Vol.48(12), pp.1790-1792
2012
DOI: 10.1039/c2cc15453f
PMID: 22215020

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Abstract

A ditopic hydrogen-bond-donor template in the form of resorcinol facilitates a [2+2] cross-photodimerisation of 4-Cl-stilbazole and 4-Me-stilbazole in a rare cocrystal solid solution. A photoreaction does not proceed with the olefins individually or as a solid solution composed solely of the two olefins.

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