Journal article
A 2D metal-organic framework with two different rhombus-shaped cavities: a rare example of a (4,4)-net with alternating metal and organic nodes
Microporous and mesoporous materials, Vol.71(1-3), pp.11-15
2004
DOI: 10.1016/j.micromeso.2004.03.008
Abstract
The synthesis and crystal structure of the metal-organic framework {[Co(acetate)2( rctt -tetrakis(4-pyridyl)cyclobutane)] · 2(methanol)}∞1) are described. The structure of 1 is based on a (4,4)-grid topology with Co(II) ions and 4,4′-tpcb cyclobutane molecules as 4-connected nodes and two different rhombus-shaped cavities in the framework. Solvent methanol molecules are clathrated between the grids. A model involving pseudo-merohedral twinning was required to arrive at a satisfactory single-crystal structure solution. Crystal data for 1: triclinic, space group P1̄, a=9.006(2), b=9.127(2), c=9.129(2), α=78.57(3), β=88.99(3), γ=88.98(3), V=735.4(3), and Z=1 for R=0.0362 (2539 reflections with I>2σ(I), 184 parameters). © 2004 Elsevier Inc. All rights reserved.
Details
- Title: Subtitle
- A 2D metal-organic framework with two different rhombus-shaped cavities: a rare example of a (4,4)-net with alternating metal and organic nodes
- Creators
- Giannis S Papaefstathiou - Department of Chemistry, University of Iowa, 423B Chemistry Building, Iowa City, Iowa 52245-1294, United StatesCostas Milios - Department of Chemistry, University of Iowa, 423B Chemistry Building, Iowa City, Iowa 52245-1294, United StatesLeonard R Macgillivray - Department of Chemistry, University of Iowa, 423B Chemistry Building, Iowa City, Iowa 52245-1294, United States
- Resource Type
- Journal article
- Publication Details
- Microporous and mesoporous materials, Vol.71(1-3), pp.11-15
- Publisher
- Elsevier
- DOI
- 10.1016/j.micromeso.2004.03.008
- ISSN
- 1387-1811
- eISSN
- 1873-3093
- Language
- English
- Date published
- 2004
- Academic Unit
- Chemistry; Pharmaceutical Sciences and Experimental Therapeutics
- Record Identifier
- 9984216699102771
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