Journal article
A Rod-Shaped Guest Leads to Architectural Isomerism in a Multicomponent Crystalline Framework Based on a Resorcin[4]arene
Crystal growth & design, Vol.1(5), pp.373-375
09/01/2001
DOI: 10.1021/cg0155245
Abstract
Cocrystallization of C-methylcalix[4]resorcinarene 1 with 4,4′-bipyridine 2 in the presence of 4-bromobiphenyl (4-brbp) yields a molecular solid, of composition 3d·(4-brbp), [where 3d = 1·2(2)], in which 1 assembles with 2 to form a one-dimensional hydrogen-bonded polymer 3d that includes two copies of the biphenyl, within elliptical cavities of dimensions ∼ 11 × 7 × 6 Å, as guests. The framework 3d represents a third architectural isomer of three previously reported supramolecular isomers of the parent material 3. © 2001 American Chemical Society.
Details
- Title: Subtitle
- A Rod-Shaped Guest Leads to Architectural Isomerism in a Multicomponent Crystalline Framework Based on a Resorcin[4]arene
- Creators
- Leonard R MacGillivray - Department of Chemistry, University of Iowa, 423B Chemistry Building, Iowa City, Iowa 52242-1294 and Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6Giannis S Papaefstathiou - Department of Chemistry, University of Iowa, 423B Chemistry Building, Iowa City, Iowa 52242-1294 and Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6Jennifer L Reid - Department of Chemistry, University of Iowa, 423B Chemistry Building, Iowa City, Iowa 52242-1294 and Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6John A Ripmeester - Department of Chemistry, University of Iowa, 423B Chemistry Building, Iowa City, Iowa 52242-1294 and Steacie Institute for Molecular Sciences, National Research Council of Canada, Ottawa, Ontario, Canada K1A 0R6
- Resource Type
- Journal article
- Publication Details
- Crystal growth & design, Vol.1(5), pp.373-375
- DOI
- 10.1021/cg0155245
- ISSN
- 1528-7483
- eISSN
- 1528-7505
- Language
- English
- Date published
- 09/01/2001
- Academic Unit
- Chemistry; Pharmaceutical Sciences and Experimental Therapeutics
- Record Identifier
- 9984216583902771
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