Journal article
A dicationic gallium-oxo-hydroxide cage compound
Acta crystallographica. Section C, Crystal structure communications, Vol.56(10), pp.1213-1215
10/2000
DOI: 10.1107/S0108270100009902
PMID: 11025300
Abstract
The crystal structure of hexa-μ-hydroxo-dodecamethylocta-μ3-oxo-dodecagallium(III) bis[tetrakis(pentafluorophenyl)borate(III)] chlorobenzene disolvate dihydrate, [Ga12(CH3)12(μ3-O)8(μ-OH)6](C24F20B)2·2C6H5Cl·2H2O, is reported. The gallium–oxo–hydroxide dication is located on an inversion center and adopts a cage structure composed of 12 fused Ga3O3 rings and is associated with the hydrate molecules and the [B(C6F5)4]− anions through hydrogen bonds and one O—H...π-ring interaction. Disordered chlorobenzene solvent molecules are also present in the crystal structure.
Details
- Title: Subtitle
- A dicationic gallium-oxo-hydroxide cage compound
- Creators
- Dale C Swenson - University of IowaSamuel Dagorne - University of ChicagoRichard F Jordan - University of Chicago
- Resource Type
- Journal article
- Publication Details
- Acta crystallographica. Section C, Crystal structure communications, Vol.56(10), pp.1213-1215
- Publisher
- Blackwell
- DOI
- 10.1107/S0108270100009902
- PMID
- 11025300
- ISSN
- 0108-2701
- eISSN
- 1600-5759
- Language
- English
- Date published
- 10/2000
- Academic Unit
- Chemistry
- Record Identifier
- 9984622746402771
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