Journal article
A multirate mass transfer model to represent the interaction of multicomponent biogeochemical processes between surface water and hyporheic zones (SWAT-MRMT-R 1.0)
Geoscientific model development, Vol.13(8), pp.3553-3569
08/07/2020
DOI: 10.5194/gmd-13-3553-2020
Abstract
Surface water quality along river corridors can be modulated by hyporheic zones (HZs) that are ubiquitous and biogeochemically active. Watershed management practices often ignore the potentially important role of HZs as a natural reactor. To investigate the effect of hydrological exchange and biogeochemical processes on the fate of nutrients in surface water and HZs, a novel model, SWAT-MRMT-R, was developed coupling the Soil and Water Assessment Tool (SWAT) watershed model and the reaction module from a flow and reactive transport code (PFLOTRAN). SWAT-MRMT-R simulates concurrent nonlinear multicomponent biogeochemical reactions in both the channel water and its surrounding HZs, connecting the channel water and HZs through hyporheic exchanges using multirate mass transfer (MRMT) representation. Within the model, HZs are conceptualized as transient storage zones with distinguished exchange rates and residence times. The biogeochemical processes within HZs are different from those in the channel water. Hyporheic exchanges are modeled as multiple first-order mass transfers between the channel water and HZs. As a numerical example, SWAT-MRMT-R is applied to the Hanford Reach of the Columbia River, a large river in the United States, focusing on nitrate dynamics in the channel water. Major nitrate contaminants entering the Hanford Reach include those from the legacy waste, irrigation return flows (irrigation water that is not consumed by crops and runs off as point sources to the stream), and groundwater seepage resulting from irrigated agriculture. A two-step reaction sequence for denitrification and an aerobic respiration reaction is assumed to represent the biogeochemical transformations taking place within the HZs. The spatially variable hyporheic exchange rates and residence times in this example are estimated with the basin-scale Networks with EXchange and Subsurface Storage (NEXSS) model. Our simulation results show that (1), given a residence time distribution, how the exchange fluxes to HZs are approximated when using MRMT can significantly change the amount of nitrate consumption in HZs through denitrification and (2) source locations of nitrate have a different impact on surface water quality due to the spatially variable hyporheic exchanges.
Details
- Title: Subtitle
- A multirate mass transfer model to represent the interaction of multicomponent biogeochemical processes between surface water and hyporheic zones (SWAT-MRMT-R 1.0)
- Creators
- Yilin Fang - Pacific Northwest National LaboratoryXingyuan Chen - Pacific Northwest National LaboratoryJesus Gomez Velez - Vanderbilt UniversityXuesong Zhang - Pacific Northwest National LaboratoryZhuoran Duan - Pacific Northwest National LaboratoryGlenn E. Hammond - Sandia National LaboratoriesAmy E. Goldman - Pacific Northwest National LaboratoryVanessa A. Garayburu-Caruso - Pacific Northwest National LaboratoryEmily B. Graham - Pacific Northwest National Laboratory
- Resource Type
- Journal article
- Publication Details
- Geoscientific model development, Vol.13(8), pp.3553-3569
- DOI
- 10.5194/gmd-13-3553-2020
- ISSN
- 1991-959X
- eISSN
- 1991-9603
- Publisher
- Copernicus Gesellschaft Mbh
- Number of pages
- 17
- Grant note
- 54737 / United States Department of Energy, Office of Science; United States Department of Energy (DOE)
- Language
- English
- Date published
- 08/07/2020
- Academic Unit
- Civil and Environmental Engineering
- Record Identifier
- 9984962626202771
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