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A solid-state trimerisation of a diene diacid affords a bicyclobutyl: reactant structure from X-ray powder data and product separation and structure determination via co-crystallisation
Journal article   Peer reviewed

A solid-state trimerisation of a diene diacid affords a bicyclobutyl: reactant structure from X-ray powder data and product separation and structure determination via co-crystallisation

Manza B J Atkinson, Ivan Halasz, Dejan-Krešimir Bučar, Robert E Dinnebier, S V Santhana Mariappan, Anatoliy N Sokolov and Leonard R MacGillivray
Chemical communications (Cambridge, England), Vol.47(1), pp.236-238
01/07/2011
DOI: 10.1039/c0cc02204g
PMID: 20820530

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Abstract

A bicyclobutyl that bears six carboxylic acid groups results from a trimerisation of a diene diacid in the solid state. Powder X-ray diffraction and a co-crystallisation are used to solve the structure of the diene and elucidate the stereochemistry of the bicyclobutyl, respectively.
Carboxylic Acids - chemistry Crystallography, X-Ray Cyclobutanes - chemical synthesis Cyclobutanes - chemistry Molecular Structure Powder Diffraction Stereoisomerism

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