Journal article
Aldehyde-Selective Wacker Oxidation in a Thiyl-Mediated Vinyl Group Transfer Route to Daunosamine
Organic letters, Vol.9(5), pp.777-780
03/01/2007
DOI: 10.1021/ol063010z
PMID: 17284042
Abstract
Asymmetric dihydroxylation, thiyl radical mediated transfer of a silicon-tethered vinyl group to a hydrazone and an unconventional aldehyde-selective Wacker oxidation are sequenced for an efficient synthesis of methyl N-trifluoroacetyl-l-daunosaminide in 32% overall yield from crotonaldehyde.
Details
- Title: Subtitle
- Aldehyde-Selective Wacker Oxidation in a Thiyl-Mediated Vinyl Group Transfer Route to Daunosamine
- Creators
- Gregory K FriestadTao JiangAlex K Mathies
- Resource Type
- Journal article
- Publication Details
- Organic letters, Vol.9(5), pp.777-780
- Publisher
- American Chemical Society
- DOI
- 10.1021/ol063010z
- PMID
- 17284042
- ISSN
- 1523-7060
- eISSN
- 1523-7052
- Language
- English
- Date published
- 03/01/2007
- Academic Unit
- Chemistry
- Record Identifier
- 9983985890402771
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