Journal article
[Am(C5Me4H)3]: An Organometallic Americium Complex
Angewandte Chemie (International ed.), Vol.58(34), pp.11695-11699
08/19/2019
DOI: 10.1002/anie.201905225
PMID: 31190446
Abstract
We report the small‐scale synthesis, isolated yield, single‐crystal X‐ray structure, 1H NMR solution spectroscopy /solid‐state UV/Vis‐nIR spectroscopy, and density functional theory (DFT)/ab initio wave function theory calculations on an Am3+ organometallic complex, [Am(C5Me4H)3] (1). This constitutes the first quantitative data on Am−C bonding in a molecular species.
Captain americium: The first structural characterization of an Am−C molecular interaction along with a suite of standard synthetic chemistry characterization techniques, including both 1H NMR and solution UV/Vis‐NIR spectroscopy have been performed. Detailed theoretical models of the electronic structure show excellent agreement with experimental data.
Details
- Title: Subtitle
- [Am(C5Me4H)3]: An Organometallic Americium Complex
- Creators
- Conrad A. P Goodwin - Los Alamos National LaboratoryJing Su - Los Alamos National LaboratoryThomas E Albrecht‐Schmitt - Florida State UniversityAnastasia V Blake - University of Iowa, E311 Chemistry BuildingEnrique R Batista - Los Alamos National LaboratoryScott R Daly - University of Iowa, E311 Chemistry BuildingStefanie Dehnen - Philipps-Universität MarburgWilliam J Evans - University of California, Irvine 1102 Natural Sciences IIAndrew J Gaunt - Los Alamos National LaboratoryStosh A Kozimor - Los Alamos National LaboratoryNiels Lichtenberger - Philipps-Universität MarburgBrian L Scott - Los Alamos National LaboratoryPing Yang - Los Alamos National Laboratory
- Resource Type
- Journal article
- Publication Details
- Angewandte Chemie (International ed.), Vol.58(34), pp.11695-11699
- DOI
- 10.1002/anie.201905225
- PMID
- 31190446
- NLM abbreviation
- Angew Chem Int Ed Engl
- ISSN
- 1433-7851
- eISSN
- 1521-3773
- Number of pages
- 5
- Grant note
- Deutscher Akademischer Austauschdienst (0) DOE Office of Science Graduate Student Research Fellowship (SCGSR) program (0) US Department of Energy, Energy Frontier Research Center (0) U.S. Department of Energy, Heavy Element Chemistry Program (0) Los Alamos National Laboratory, LDRD-ER program (0)
- Language
- English
- Date published
- 08/19/2019
- Academic Unit
- Chemistry
- Record Identifier
- 9984216567002771
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