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Amine modification of nonporous silica nanoparticles reduces inflammatory response following intratracheal instillation in murine lungs
Journal article   Open access   Peer reviewed

Amine modification of nonporous silica nanoparticles reduces inflammatory response following intratracheal instillation in murine lungs

Angie S Morris, Andrea Adamcakova-Dodd, Sean E Lehman, Amaraporn Wongrakpanich, Peter S Thorne, Sarah C Larsen and Aliasger K Salem
Toxicology letters, Vol.241, pp.207-215
01/22/2016
DOI: 10.1016/j.toxlet.2015.11.006
PMCID: PMC4691407
PMID: 26562768
url
https://doi.org/10.1016/j.toxlet.2015.11.006View
Published (Version of record) Open Access

Abstract

•We investigated nonporous silica NPs both bare and modified with amine functional groups (3-aminopropyltriethoxysilane (APTES)) in order to evaluate the effect of surface chemistry on biocompatibility.•No cytotoxicity was observed in a human lung cancer epithelial cell line (A549) for bare silica NPs or amine-functionalized silica NPs.•Bare silica NPs elicited a significantly higher inflammatory response compared to amine-functionalized NPs. Amorphous silica nanoparticles (NPs) possess unique material properties that make them ideal for many different applications. However, the impact of these materials on human and environmental health needs to be established. We investigated nonporous silica NPs both bare and modified with amine functional groups (3-aminopropyltriethoxysilane (APTES)) in order to evaluate the effect of surface chemistry on biocompatibility. In vitro data showed there to be little to no cytotoxicity in a human lung cancer epithelial cell line (A549) for bare silica NPs and amine-functionalized NPs using doses based on both mass concentration (below 200μg/mL) and exposed total surface area (below 14m2/L). To assess lung inflammation, C57BL/6 mice were administered bare or amine-functionalized silica NPs via intra-tracheal instillation. Two doses (0.1 and 0.5mg NPs/mouse) were tested using the in vivo model. At the higher dose used, bare silica NPs elicited a significantly higher inflammatory response, as evidence by increased neutrophils and total protein in bronchoalveolar lavage (BAL) fluid compared to amine-functionalized NPs. From this study, we conclude that functionalization of nonporous silica NPs with APTES molecules reduces murine lung inflammation and improves the overall biocompatibility of the nanomaterial.
Nanomaterials Inflammation A549 cells Nanotoxicology Amine-functionalized silica

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