Journal article
An Intramolecular OH···π(arene) Interaction in a BINOL–Phenazine Cocrystal with a “Free” N-Atom
Crystal growth & design, Vol.18(7), pp.3890-3895
07/05/2018
DOI: 10.1021/acs.cgd.8b00199
Abstract
We report the occurrence of the hydrogen-bond donor molecule 1,1′-binaphthyl-2,2′-diol (BINOL) that in the presence of the appreciably strong hydrogen-bond acceptor phenazine forms a cocrystal stabilized by weak OH···π(arene) interactions. We also present a survey of the Cambridge Structural Database involving BINOL that reveals a limited number of structures that demonstrate the presence of a hydrogen-bond acceptor group viz-a-viz phenazine that does not participate in a traditional hydrogen bond with BINOL.
Details
- Title: Subtitle
- An Intramolecular OH···π(arene) Interaction in a BINOL–Phenazine Cocrystal with a “Free” N-Atom
- Creators
- Katherine E Peterson - Research and Development, AbbVie, Inc., North Chicago, Illinois 60064, United States, Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, United StatesRodger F Henry - Research and Development, AbbVie, Inc., North Chicago, Illinois 60064, United StatesGeoff G. Z Zhang - Research and Development, AbbVie, Inc., North Chicago, Illinois 60064, United StatesLeonard R MacGillivray - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, United States
- Resource Type
- Journal article
- Publication Details
- Crystal growth & design, Vol.18(7), pp.3890-3895
- DOI
- 10.1021/acs.cgd.8b00199
- ISSN
- 1528-7483
- eISSN
- 1528-7505
- Grant note
- DOI: 10.13039/100006483, name: AbbVie; DOI: 10.13039/100000078, name: Division of Materials Research, award: DMR-1708673
- Language
- English
- Date published
- 07/05/2018
- Academic Unit
- Chemistry; Pharmaceutical Sciences and Experimental Therapeutics
- Record Identifier
- 9984216714302771
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