Journal article
Application of a tetrapyrimidyl cyclobutane synthesized in the organic solid state: a halogen-bonded supramolecular ladder
CrystEngComm, Vol.22(41), pp.678-6782
10/26/2020
DOI: 10.1039/d0ce01280g
Abstract
A halogen-bonded supramolecular ladder comprised of a novel pyrimidine-based cyclobutane photoproduct synthesized in the organic solid state
via
a [2 + 2] photoreaction is reported. The photoproduct
rctt
-tetrakis(5′-pyrimidyl)cyclobutane functions as rungs while the linear divergent halogen-bond donor 1,4-diiodoperchlorobenzene acts as the rails. Our report also confirms the structure and stereochemistry of the tetrapyrimidyl cyclobutane ring system.
A supramolecular ladder sustained by halogen bonds with rungs based upon a photoproduct, namely
rctt
-tetrakis(5′-pyrimidyl)cylcobutane, generated in the solid state is reported.
Details
- Title: Subtitle
- Application of a tetrapyrimidyl cyclobutane synthesized in the organic solid state: a halogen-bonded supramolecular ladder
- Creators
- Michael A SinnwellCarlos L SantanaEric BoschLeonard R MacGillivrayRyan H Groeneman
- Resource Type
- Journal article
- Publication Details
- CrystEngComm, Vol.22(41), pp.678-6782
- DOI
- 10.1039/d0ce01280g
- ISSN
- 1466-8033
- eISSN
- 1466-8033
- Number of pages
- 3
- Grant note
- DOI: 10.13039/100000001, name: National Science Foundation, award: DMR-1708673
- Language
- English
- Date published
- 10/26/2020
- Academic Unit
- Chemistry; Pharmaceutical Sciences and Experimental Therapeutics
- Record Identifier
- 9984216679002771
Metrics
7 Record Views