Journal article
Channel Confinement of Aromatic Petrochemicals via Aryl–Perfluoroaryl Interactions With a B←N Host
Frontiers in chemistry, Vol.7, pp.695-695
10/22/2019
DOI: 10.3389/fchem.2019.00695
PMCID: PMC6818625
PMID: 31696109
Abstract
We report channel confinement properties of an electron-deficient boron host derived from the orthogonal B←N interaction between a boronic ester and
trans
-pentafluorostilbazole. The boron host forms one-dimensional channels in the crystalline solid state when crystallized with common electron-rich aromatic petrochemicals (i.e., benzene, toluene,
o
-xylene) to form solvates and a cocrystal with stilbene. Molecular confinement of the electron-rich molecules in the solids is achieved through a combination of aryl–perfluoroaryl interactions (π-π
F
) and hydrogen bonds.
Details
- Title: Subtitle
- Channel Confinement of Aromatic Petrochemicals via Aryl–Perfluoroaryl Interactions With a B←N Host
- Creators
- Gonzalo Campillo-Alvarado - , , , ,Megan M D'mello - , , , ,Michael A Sinnwell - , , , ,Herbert Höpfl - , , , ,Hugo Morales-Rojas - , , , ,Leonard R MacGillivray - , , , ,
- Resource Type
- Journal article
- Publication Details
- Frontiers in chemistry, Vol.7, pp.695-695
- DOI
- 10.3389/fchem.2019.00695
- PMID
- 31696109
- PMCID
- PMC6818625
- NLM abbreviation
- Front Chem
- ISSN
- 2296-2646
- eISSN
- 2296-2646
- Publisher
- Frontiers Media S.A
- Grant note
- L.R.M. DMR-1708673 / National Science Foundation Consejo Nacional de Ciencia y Tecnología
- Language
- English
- Date published
- 10/22/2019
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216725102771
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