Journal article
Characteristics of polychlorinated biphenyl (PCB) atropisomers
Chemosphere (Oxford), Vol.15(9), pp.2061-2064
1986
DOI: 10.1016/0045-6535(86)90513-8
Abstract
We have prepared and characterized the atropisomers of 3 PCBs, namely 2,2′,3,4,6-penta-[I],2,2′,3,4,4′,6-hexa-[II] and 2,2′,3,3′,4,4′,6,6′-octachlorobiphenyls [III]. On the basis of the rotational stability of these 3 enantiomer pairs, we can predict that, of the 78 PCBs which possess axial chirality, the enantiomers of at least 19 PCBs containing 3 or 4 ortho chlorines would be stable to racemization at room temperature.
Details
- Title: Subtitle
- Characteristics of polychlorinated biphenyl (PCB) atropisomers
- Creators
- M. Püttmann - Johannes Gutenberg University MainzF. Oesch - Johannes Gutenberg University MainzL.W. RobertsonA. Mannschreck - University of Regensburg
- Resource Type
- Journal article
- Publication Details
- Chemosphere (Oxford), Vol.15(9), pp.2061-2064
- Publisher
- Elsevier Ltd
- DOI
- 10.1016/0045-6535(86)90513-8
- ISSN
- 0045-6535
- eISSN
- 1879-1298
- Grant note
- DOI: 10.13039/501100001659, name: Deutsche Forschungsgemeinschaft, award: SFB 302
- Language
- English
- Date published
- 1986
- Academic Unit
- Occupational and Environmental Health
- Record Identifier
- 9984363628702771
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