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Chemistry of diagenetic features analyzed by ChemCam at Pahrump Hills, Gale Crater, Mars
Journal article   Peer reviewed

Chemistry of diagenetic features analyzed by ChemCam at Pahrump Hills, Gale Crater, Mars

Marion Nachon, Nicolas Mangold, Olivier Forni, L. C. Kah, A. Cousin, R. C. Wiens, R. Anderson, D. Blaney, J. G. Blank, F. Calef, …
Icarus (New York, N.Y. 1962), Vol.281(C), pp.121-136
01/01/2017
DOI: 10.1016/j.icarus.2016.08.026
url
https://www.osti.gov/servlets/purl/1412864View
Open Access

Abstract

The Curiosity rover's campaign at Pahrump Hills provides the first analyses of lower Mount Sharp strata. Here we report ChemCam elemental composition of a diverse assemblage of post-depositional features embedded in, or cross-cutting, the host rock. ChemCam results demonstrate their compositional diversity, especially compared to the surrounding host rock: (i) Dendritic aggregates and relief enhanced features, characterized by a magnesium enhancement and sulfur detection, and interpreted as Mg-sulfates; (ii) A localized observation that displays iron enrichment associated with sulfur, interpreted as Fe-sulfate; (iii) Dark raised ridges with varying Mg- and Ca-enriched compositions compared to host rock; (iv) Several dark-toned veins with calcium enhancement associated with fluorine detection, interpreted as fluorite veins. (v) Light-toned veins with enhanced calcium associated with sulfur detection, and interpreted as Ca-sulfates. The diversity of the Pahrump Hills diagenetic assemblage suggests a complex post-depositional history for fine-grained sediments for which the origin has been interpreted as fluvial and lacustrine. Assessment of the spatial and relative temporal distribution of these features shows that the Mg-sulfate features are predominant in the lower part of the section, suggesting local modification of the sediments by early diagenetic fluids. In contrast, light-toned Ca-sulfate veins occur in the whole section and cross-cut all other features. A relatively late stage shift in geochemical conditions could explain this observation. The Pahrump Hills diagenetic features have no equivalent compared to targets analyzed in other locations at Gale crater. Only the light-toned Ca-sulfate veins are present elsewhere, along Curiosity's path, suggesting they formed through a common late-stage process that occurred at over a broad area.
Fluorides Iron alkaline earth metals aqueous alteration calcium calcium sulfate ChemCam chemical composition Curiosity Rover diagenesis Extraterrestrial geology fluorite Gale Crater halides iron sulfates magnesium magnesium sulfates Mars Mars Science Laboratory metals Mount Sharp Pahrump Hills planets spatial distribution sulfates sulfur temporal distribution terrestrial planets textures veins

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