Journal article
Chronopotentiometry in thin-layer electrochemical cells: a new look at transition–time derivations including multicomponent systems
Journal of electroanalytical chemistry (Lausanne, Switzerland), Vol.543(1), pp.13-22
2003
DOI: 10.1016/S0022-0728(02)01414-6
Abstract
A complete derivation is presented for concentration profiles and transition times in a thin layer cell under constant current conditions. Expressions for the concentration across a thin layer cell and the transition time are presented under conditions where the diffusion layer is extremely small (short times) and extremely large (long times) compared to the thickness of the thin layer cell. Excellent agreement with those previously reported in the literature is found. Application to thin layer spectroelectrochemical cells is demonstrated.
Details
- Title: Subtitle
- Chronopotentiometry in thin-layer electrochemical cells: a new look at transition–time derivations including multicomponent systems
- Creators
- Johna Leddy - Department of Chemistry, University of Iowa, Iowa City, IA 52242, USACynthia G Zoski - Department of Chemistry, Georgia State University, University Plaza, Atlanta, GA 30303, USA
- Resource Type
- Journal article
- Publication Details
- Journal of electroanalytical chemistry (Lausanne, Switzerland), Vol.543(1), pp.13-22
- Publisher
- Elsevier B.V
- DOI
- 10.1016/S0022-0728(02)01414-6
- ISSN
- 1572-6657
- eISSN
- 1873-2569
- Language
- English
- Date published
- 2003
- Academic Unit
- Chemistry
- Record Identifier
- 9984216709702771
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