Journal article
Combination of Argentophilic and Perfluorophenyl-Perfluorophenyl Interactions Supports a Head-to-Head [2 + 2] Photodimerization in the Solid State
Crystal growth & design, Vol.15(2), pp.538-541
02/04/2015
DOI: 10.1021/cg501571u
Abstract
Face-to-face perfluorophenyl-perfluorophenyl interactions (C6F5⋯C6F5) are achieved in a disilver metal-organic complex. The C6F5⋯C6F5 interactions along with argentophilic forces support trans-pentafluorostilbazole to undergo a head-to-head [2 + 2] photodimerization to form a cyclobutane that sustains a fluorinated two-dimensional metal-organic framework.
Details
- Title: Subtitle
- Combination of Argentophilic and Perfluorophenyl-Perfluorophenyl Interactions Supports a Head-to-Head [2 + 2] Photodimerization in the Solid State
- Creators
- Michael A Sinnwell - Department of Chemistry, University of Iowa, Iowa City, Iowa, United StatesJonas Baltrusaitis - Department of Chemical and Biomolecular Engineering, Lehigh University, Bethlehem, Pennsylvania, United StatesLeonard R MacGillivray - Department of Chemistry, University of Iowa, Iowa City, Iowa, United States
- Resource Type
- Journal article
- Publication Details
- Crystal growth & design, Vol.15(2), pp.538-541
- DOI
- 10.1021/cg501571u
- ISSN
- 1528-7483
- eISSN
- 1528-7505
- Grant note
- DOI: 10.13039/100000078, name: Division of Materials Research, award: DMR-1408834
- Language
- English
- Date published
- 02/04/2015
- Academic Unit
- Chemistry; Pharmaceutical Sciences and Experimental Therapeutics
- Record Identifier
- 9984216714002771
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