Journal article
Communication—Voltammetry of Lanthanide (III) Triflates Accessible in Acetonitrile at Nafion Modified Electrodes
Journal of the Electrochemical Society, Vol.168(6), p.66511
06/08/2021
DOI: 10.1149/1945-7111/ac0649
Abstract
Lanthanides are common in catalysis and advanced technologies, but difficult to assess voltammetrically. Voltammetry for seven lanthanide(III) trifluoromethanesulfonate complexes Ln(OTf)3 is enabled at Nafion® modified platinum electrodes in acetonitrile. Voltammetric morphologies for La3+, Pr3+, Nd3+, Sm3+, Gd3+, Dy3+, and Yb3+ trifluoromethanesulfonate (triflate) complexes exhibit reduction waves between 0.2 to 0.1 V and -0.7 to -0.8 V vs NHE with coupled chemical processes.
Details
- Title: Subtitle
- Communication—Voltammetry of Lanthanide (III) Triflates Accessible in Acetonitrile at Nafion Modified Electrodes
- Creators
- Krysti L Knoche Gupta - University of Wisconsin-Eau Claire , Department of Chemistry and Biochemistry, Eau Claire, Wisconsin 54701, United States of AmericaNadeesha P. W Rathuwadu - General Sir John Kotelawala Defence University Institute for Combinatorial Advanced Research & Education, Sri LankaJohna Leddy - University of Iowa , Department of Chemistry, Iowa City, Iowa 52242, United States of America
- Resource Type
- Journal article
- Publication Details
- Journal of the Electrochemical Society, Vol.168(6), p.66511
- DOI
- 10.1149/1945-7111/ac0649
- ISSN
- 0013-4651
- eISSN
- 1945-7111
- Publisher
- IOP Publishing
- Number of pages
- 3
- Grant note
- CHE-1309366 / National Science Foundation (https://doi.org/10.13039/100000001)
- Language
- English
- Date published
- 06/08/2021
- Academic Unit
- Chemistry
- Record Identifier
- 9984216702302771
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