Journal article
Comparative studies of palladium and copper-catalysed [gamma]-arylation of silyloxy furans with diaryliodonium salts
Tetrahedron, Vol.75(14), p.2229
04/05/2019
DOI: 10.1016/j.tet.2019.02.042
Abstract
The [gamma]-arylation of substituted silyl-activated butenolides has been studied using a broad scope of unsymmetrical hypervalent diaryliodonium salts via a palladium- or copper-catalysed coupling reaction, yielding interesting reactivity trends. The mild catalytic conditions and coupling partner variability provide access to synthetically useful building blocks toward the pursuit of aryl-lactone containing natural products and allows for facile diversification.
Details
- Title: Subtitle
- Comparative studies of palladium and copper-catalysed [gamma]-arylation of silyloxy furans with diaryliodonium salts
- Creators
- Taylor S AlexanderTravis J ClayBryan MaldonadoJohny M NguyenDavid B.C Martin
- Resource Type
- Journal article
- Publication Details
- Tetrahedron, Vol.75(14), p.2229
- Publisher
- Elsevier B.V
- DOI
- 10.1016/j.tet.2019.02.042
- ISSN
- 0040-4020
- eISSN
- 1464-5416
- Grant note
- DOI: 10.13039/100000001, name: NSF, award: CHE-1626673; DOI: 10.13039/100009918, name: U.S. Army, award: W911NF-16-1-0523; DOI: 10.13039/100000001, name: NSF, award: CHE-0541848
- Language
- English
- Date published
- 04/05/2019
- Description audience
- Academic
- Academic Unit
- Chemistry; Iowa Neuroscience Institute
- Record Identifier
- 9984065856602771
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