Journal article
Crystal and molecular structure of 1,1′-ferrocene-dicarbaldehyde
Journal of chemical crystallography, Vol.29(8), pp.865-869
08/1999
DOI: 10.1023/A:1009568409349
Abstract
The crystal and molecular structure of 1,1′-ferrocene-dicarbaldehyde 1 is reported. Crystal data for 1: monoclinic, space group P21/n, a = 5.876(1), b = 11.349(1), c = 29.460(3) Å,β = 95.067(2)°, V = 1956.9(3) Å3, and D
c = 1.64 g/cm3, for Z = 8. The complex crystallizes such that two molecules are located in the asymmetric unit in which the complexes display different degrees of twisting of the cyclopentadienyl (Cp) rings and formyl substituents about the Cp—Fe—Cp and Cp—COH axes, respectively. The molecule self-assembles in the solid state to form a 2D layered structure held together by π-π interactions and C—H···O hydrogen bonds.
Details
- Title: Subtitle
- Crystal and molecular structure of 1,1′-ferrocene-dicarbaldehyde
- Creators
- Leonard MacGillivray - Steacie Institute for Molecular Sciences National Research Council of Canada Ottawa Ontario Canada K1A 0R6Heather Spinney - Steacie Institute for Molecular Sciences National Research Council of Canada Ottawa Ontario Canada K1A 0R6Jennifer Reid - Steacie Institute for Molecular Sciences National Research Council of Canada Ottawa Ontario Canada K1A 0R6John Ripmeester - Steacie Institute for Molecular Sciences National Research Council of Canada Ottawa Ontario Canada K1A 0R6
- Resource Type
- Journal article
- Publication Details
- Journal of chemical crystallography, Vol.29(8), pp.865-869
- Publisher
- Kluwer Academic Publishers-Plenum Publishers
- DOI
- 10.1023/A:1009568409349
- ISSN
- 1074-1542
- eISSN
- 1572-8854
- Language
- English
- Date published
- 08/1999
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216671302771
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