Journal article
Crystal and molecular structure of 2,7-di-tert-butyl-9,9-dimethyl-4,5-xanthenedicarboxylic acid
Journal of chemical crystallography, Vol.31(7), pp.373-376
08/2001
DOI: 10.1023/A:1015603507044
Abstract
The crystal and molecular structure of molecular cleft 2,7-di-tert-butyl-9,9-dimethyl-4,5-xanthenedicarboxylic acid (1) is reported. Crystal data for 1: triclinic, space group Pī, a = 7.934(2), b = 10.387(2), c = 14.084(3) Å, α = 96.049(3), β = 101.231(4), γ = 95.635(4)°, V = 1123.7(4) Å3, and D
c = 1.21 g/cm3, for Z = 2. The molecule crystallizes as a cyclic, hydrogen-bonded dimer held together by four O–H······O hydrogen bonds involving four carboxyl groups each of which interact by way of a cyclic hydrogen-bonded motif. The complex organizes in the solid state to form a 2D layered structure.
Details
- Title: Subtitle
- Crystal and molecular structure of 2,7-di-tert-butyl-9,9-dimethyl-4,5-xanthenedicarboxylic acid
- Creators
- Leonard MacGillivray - Department of Chemistry University of Iowa Iowa City Iowa 52242-1294Michelle Siebke - Department of Chemistry University of Iowa Iowa City Iowa 52242-1294
- Resource Type
- Journal article
- Publication Details
- Journal of chemical crystallography, Vol.31(7), pp.373-376
- Publisher
- Kluwer Academic Publishers-Plenum Publishers
- DOI
- 10.1023/A:1015603507044
- ISSN
- 1074-1542
- eISSN
- 1572-8854
- Language
- English
- Date published
- 08/2001
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216579202771
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