Journal article
Crystal and molecular structure of [Cu2(3,5-dihydroxybenzoate)4 (acetonitrile)2] ⋅ 8H2O
Journal of chemical crystallography, Vol.32(7), pp.191-195
07/2002
DOI: 10.1023/A:1020291903742
Abstract
The crystal and molecular structure of the title compound, [Cu2(3,5-dihydroxybenzoate)4 (acetonitrile)2] ⋅ 8H2O 1, is reported. Crystal data for 1: tetragonal, space group I 4/m, a = 11.720(2) Å, c = 15.304(3) Å, V = 2102.4(6), and D
c = 1.53 g/cm3, for Z = 2. The metal and organic components crystallize to form a Cu paddle-wheel complex, of idealized D4h symmetry, that assembles in the solid-state, along with eight equivalents of water, to form a 3D hydrogen-bonded network held together by O–H ⋅⋅⋅ O hydrogens bonds. The metal complexes pack to form a 2D layered structure.
Details
- Title: Subtitle
- Crystal and molecular structure of [Cu2(3,5-dihydroxybenzoate)4 (acetonitrile)2] ⋅ 8H2O
- Creators
- Giannis Papaefstathiou - Department of Chemistry University of Iowa Iowa City Iowa 52242Brett Darrow - Department of Chemistry University of Iowa Iowa City Iowa 52242Leonard MacGillivray - Department of Chemistry University of Iowa Iowa City Iowa 52242
- Resource Type
- Journal article
- Publication Details
- Journal of chemical crystallography, Vol.32(7), pp.191-195
- Publisher
- Kluwer Academic Publishers-Plenum Publishers
- DOI
- 10.1023/A:1020291903742
- ISSN
- 1074-1542
- eISSN
- 1572-8854
- Language
- English
- Date published
- 07/2002
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216614402771
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