Journal article
Crystal structure of (±)-2-[4-(4-chlorophenoxymethyl)phenoxy]propionic acid
Australian journal of chemistry, Vol.35(10), pp.2151-2155
1982
DOI: 10.1071/CH9822151
Abstract
The crystal structure of ( )-2-[4-(4-chlorophenoxymethyl)phenoxy]propionic acid has been
determined by direct methods using three-dimensional X-ray diffraction data.
The crystals are triclinic, P1, Z 2, a 9.345(2),
b 12,602(2), c 6.741(1) , α 101.37(1), β 97.42(1), γ 101.75(1) .
The structure refined to give a final R 0.084 for 2172 observed reflections.
The acid molecules form centrosymmetric hydrogen
bonded cyclic dimers [O. . .O,2.619(4) ] about a centre of symmetry in the
cell. The oxopropionic acid side chain has a synplanar-synplanar
(carbonyl) conformation while the planar p-chlorophenoxymethyl substituent in the p-position has a synclinal orientation relative to the primary phenoxy residue.
Details
- Title: Subtitle
- Crystal structure of (±)-2-[4-(4-chlorophenoxymethyl)phenoxy]propionic acid
- Creators
- G SmithCHL KennardW L DuaxD C Swenson
- Resource Type
- Journal article
- Publication Details
- Australian journal of chemistry, Vol.35(10), pp.2151-2155
- DOI
- 10.1071/CH9822151
- ISSN
- 0004-9425
- eISSN
- 1445-0038
- Language
- English
- Date published
- 1982
- Academic Unit
- Chemistry
- Record Identifier
- 9984622048802771
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