Journal article
Cubane-forming cyclic dienes that exhibit orthogonal reactivities in the solid state
Chemical communications (Cambridge, England), Vol.57(55), pp.6725-6727
07/08/2021
DOI: 10.1039/D1CC02725E
PMID: 34126633
Abstract
Photoirradiation of a binary cocrystal composed of two different cyclic dienes generates a highly-symmetric cubane-like tetraacid cage regioselectively and in quantitative yield. The cage forms by a double [2+2] photodimerization of one of the diene cocrystal components. The second diene while photostable in the cocrystal reacts in a double [2+2] photodimerization as a pure form quantitatively to form a tetramethyl cubane-like cage. The stereochemistry of the cage is structurally authenticated.
Details
- Title: Subtitle
- Cubane-forming cyclic dienes that exhibit orthogonal reactivities in the solid state
- Creators
- Changan Li - Department of Chemistry, University of Iowa, Iowa City, USAMichael A Sinnwell - Department of Chemistry, University of Iowa, Iowa City, USADale C Swenson - Department of Chemistry, University of Iowa, Iowa City, USALeonard R MacGillivray - Department of Chemistry, University of Iowa, Iowa City, USA
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.57(55), pp.6725-6727
- DOI
- 10.1039/D1CC02725E
- PMID
- 34126633
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry
- Grant note
- DOI: 10.13039/100000165, name: Division of Chemistry, award: 1828117; DOI: 10.13039/100000078, name: Division of Materials Research, award: 1708673; DOI: 10.13039/100012011, name: Graduate College, University of Iowa
- Language
- English
- Date published
- 07/08/2021
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216570502771
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