Journal article
Cyclic (1R,3R)-1,3-dimethyltrimethylene [(5R)-2-hydroxy-5-methyl-5-(2-methyl-1,3-dioxolan-2-yl)-1-cyclohexen-1-yl]-phosphonate, a stable enol
Acta crystallographica. Section C, Crystal structure communications, Vol.51(3), pp.479-482
1995
DOI: 10.1107/S0108270194010164
PMID: 7734089
Abstract
The title compound, C16H27O6P, was obtained from the rearrangement of the corresponding vinyl phosphate. 31P NMR experiments in solution have shown that this compound equilibrates to a mixture of three isomers in nearly equal proportions. In the crystalline state a single isomer is found which diffraction analysis identified as the enol form of the beta-keto phosphonate having R stereochemistry at atom C(8).
Details
- Title: Subtitle
- Cyclic (1R,3R)-1,3-dimethyltrimethylene [(5R)-2-hydroxy-5-methyl-5-(2-methyl-1,3-dioxolan-2-yl)-1-cyclohexen-1-yl]-phosphonate, a stable enol
- Creators
- Mark A Capron - Univ. Iowa, dep. chemistry, Iowa City IA 52242, United StatesJIANGUO AN - Univ. Iowa, dep. chemistry, Iowa City IA 52242, United StatesDale C Swenson - Univ. Iowa, dep. chemistry, Iowa City IA 52242, United StatesDavid F Wiemer - Univ. Iowa, dep. chemistry, Iowa City IA 52242, United States
- Resource Type
- Journal article
- Publication Details
- Acta crystallographica. Section C, Crystal structure communications, Vol.51(3), pp.479-482
- Publisher
- Blackwell
- DOI
- 10.1107/S0108270194010164
- PMID
- 7734089
- ISSN
- 0108-2701
- eISSN
- 1600-5759
- Language
- English
- Date published
- 1995
- Academic Unit
- Neuroscience and Pharmacology; Chemistry
- Record Identifier
- 9984216604702771
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