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Direct Measure of Strain and Electronic Structure in GaAs/GaP Core—Shell Nanowires
Journal article   Peer reviewed

Direct Measure of Strain and Electronic Structure in GaAs/GaP Core—Shell Nanowires

Mohammad Montazeri, Melodie Fickenscher, JIN Zou, Mats-Erik Pistol, Craig E Pryor, Leigh M Smith, Howard E Jackson, Jan YARRISON-RICE, JUNG HYUN Kang, QIANG Gao, …
Nano letters, Vol.10(3), pp.880-886
2010
DOI: 10.1021/nl903547r
PMID: 20131863
url
https://openresearch-repository.anu.edu.au/bitstreams/e746905f-5670-4596-bd7d-b76d6d8122fb/downloadView
Open Access

Abstract

Highly strained GaAs/GaP nanowires of excellent optical quality were grown with 50 nm diameter GaAs cores and 25 nm GaP shells. Photoluminescence from these nanowires is observed at energies dramatically shifted from the unstrained GaAs free exciton emission energy by 260 meV. Using Raman scattering, we show that it is possible to separately measure the degree of compressive and shear strain of the GaAs core and show that the Raman response of the GaP shell is consistent with tensile strain. The Raman and photoluminescence measurement are both on good agreement with 8 band k.p calculations. This result opens up new possibilities for engineering the electronic properties of the nanowires for optimal design of one-dimensional nanodevices by controlling the strain of the core and shell by varying the nanowire geometry.
Materials Science Physics Condensed matter: electronic structure, electrical, magnetic, and optical properties Cross-disciplinary physics: materials science; rheology Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures Electronic structure of nanoscale materials : clusters, nanoparticles, nanotubes, and nanocrystals Exact sciences and technology Nanocrystalline materials Nanoscale materials and structures: fabrication and characterization Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation Optical properties of low-dimensional, mesoscopic, and nanoscale materials and structures Quantum wires

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