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Direct Observation of Li+ Ions Trapped in a Mg2+-Templated Metal-Organic Framework
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Direct Observation of Li+ Ions Trapped in a Mg2+-Templated Metal-Organic Framework

Yi Han, Kang Liu, Michael A. Sinnwell, Lili Liu, Hongliang Huang and Praveen K. Thallapally
Inorganic chemistry, Vol.58(14), pp.8922-8926
07/15/2019
DOI: 10.1021/acs.inorgchem.9b01207
PMID: 31247838

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Abstract

Herein we report the first example of a metal-organic framework (MOF) in which the location of Li+ ions trapped in the porous confinement can be unambiguously defined by single-crystal X-ray diffraction. Furthermore, the Li+-doped MOF shows significant enhancement in gas uptake as well as selective adsorption of CO2 over CH4.
Physical Sciences Chemistry Chemistry, Inorganic & Nuclear Science & Technology

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