Journal article
Discrete versus Infinite Molecular Self-Assembly: Control in Crystalline Hydrogen-Bonded Assemblies Based on Resorcinol
Organic letters, Vol.3(24), pp.3835-3838
11/01/2001
DOI: 10.1021/ol0165948
PMID: 11720548
Abstract
equation presented Cocrystallization of 1,2-bis(4-pyridyl)ethane (4,4′-bipyeth) with resorcinol (res), 4-chlororesorcinol (4-Cl-res), and 4,6-dichlororesorcinol (4,6-di-Cl-res) yields molecular solids (4,4′-bipyeth)·(res) 1a, 2(4,4′-bipyeth)·2(4-Cl-res) 1b, and 2(4,4′-bipyeth)·2(4,6-di-Cl-res) 1c with components held together by O-H⋯-N hydrogen bonds. In 1a the components form an infinite 1D polar array, whereas in 1b and 1c the components form 0D four-component complexes. Formation of the discrete assemblies is attributed to peripheral steric effects, which block the solid-state polymerization.
Details
- Title: Subtitle
- Discrete versus Infinite Molecular Self-Assembly: Control in Crystalline Hydrogen-Bonded Assemblies Based on Resorcinol
- Creators
- Giannis S Papaefstathiou - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242-1294Leonard R MacGillivray - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242-1294
- Resource Type
- Journal article
- Publication Details
- Organic letters, Vol.3(24), pp.3835-3838
- DOI
- 10.1021/ol0165948
- PMID
- 11720548
- ISSN
- 1523-7060
- eISSN
- 1523-7052
- Language
- English
- Date published
- 11/01/2001
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216688402771
Metrics
11 Record Views