Journal article
Double inclusion of ferrocene within a doubly interpenetrated three-dimensional framework based on a resorcin[4]arene
Journal of organometallic chemistry, Vol.666(1), pp.43-48
2003
DOI: 10.1016/S0022-328X(02)02031-4
Abstract
Co-crystallization of
C-methylcalix[4]resorcinarene (
1) and 4,4′-bipyridine (
2) from ethanol in the presence of ferrocene affords single crystals of
3h·2.15 (ethanol)·0.85 (ferrocene) that consist of a doubly interpenetrated 3D hydrogen-bonded framework,
1·1.5(
2) (
3h). The 3D framework
3h is a supramolecular isomer of a reported 2D framework
3g and possesses box-shaped cavities that include two molecules of ferrocene as a guest.
A doubly interpenetrated 3D hydrogen-bonded framework based on resorcin[4]arene is revealed to accommodate two molecules of ferrocene within box-shaped cavities of nanometer-scale dimensions.
Details
- Title: Subtitle
- Double inclusion of ferrocene within a doubly interpenetrated three-dimensional framework based on a resorcin[4]arene
- Creators
- Tomislav FriščićLeonard R MacGillivray
- Resource Type
- Journal article
- Publication Details
- Journal of organometallic chemistry, Vol.666(1), pp.43-48
- Publisher
- Elsevier B.V
- DOI
- 10.1016/S0022-328X(02)02031-4
- ISSN
- 0022-328X
- eISSN
- 1872-8561
- Language
- English
- Date published
- 2003
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216703702771
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