Journal article
Dramatic Red-Shifted Fluorescence of [2.2]Paracyclophanes with Peripheral Substituents Attached to the Saturated Bridges
Organic letters, Vol.11(22), pp.5106-5109
11/19/2009
DOI: 10.1021/ol901907j
PMID: 19852498
Abstract
A bridge-substituted [2.2]paracyclophane obtained from the organic solid state exhibits a dramatic red shift in fluorescence relative to [2.2]paracyclophane. A further red shift occurs upon alkylation of the pyridylcyclobutyl bridges. Our results demonstrate that [2.2]cyclophanes substituted at the bridge, despite not being attached via the extended π-system, are promising building blocks in the development of optical materials © 2009 American Chemical Society.
Details
- Title: Subtitle
- Dramatic Red-Shifted Fluorescence of [2.2]Paracyclophanes with Peripheral Substituents Attached to the Saturated Bridges
- Creators
- Elizabeth Elacqua - Department of Chemistry and The Optical Science and Technology Center, University of Iowa, Iowa City, Iowa 52242Dejan-Krešimir Bučar - Department of Chemistry and The Optical Science and Technology Center, University of Iowa, Iowa City, Iowa 52242Yulia Skvortsova - Department of Chemistry and The Optical Science and Technology Center, University of Iowa, Iowa City, Iowa 52242Jonas Baltrusaitis - Department of Chemistry and The Optical Science and Technology Center, University of Iowa, Iowa City, Iowa 52242M. Lei Geng - Department of Chemistry and The Optical Science and Technology Center, University of Iowa, Iowa City, Iowa 52242Leonard R MacGillivray - Department of Chemistry and The Optical Science and Technology Center, University of Iowa, Iowa City, Iowa 52242
- Resource Type
- Journal article
- Publication Details
- Organic letters, Vol.11(22), pp.5106-5109
- DOI
- 10.1021/ol901907j
- PMID
- 19852498
- ISSN
- 1523-7060
- eISSN
- 1523-7052
- Language
- English
- Date published
- 11/19/2009
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216572002771
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