Journal article
Enantioselective synthesis of α-hydroxy phosphonates via oxidation with (camphorsulfonyl)oxaziridines
Tetrahedron letters, Vol.38(20), pp.3495-3498
1997
DOI: 10.1016/S0040-4039(97)00705-3
Abstract
Reaction of phosphonate anions with enantiomerically pure (camphorsulfonyl)oxaziridines results in formation of nonracemic α-hydroxy phosphonates. This enantioselective hydroxylation methodology provides convenient access to optically active α-hydroxy phosphonates and their corresponding phosphonic acids. Oxidation of benzylphosphonate anions with enantiomerically pure (camphorsulfonyl)oxaziridines results in formation of nonracemic α-hydroxy phosphonates in good enantiomeric excess.
Details
- Title: Subtitle
- Enantioselective synthesis of α-hydroxy phosphonates via oxidation with (camphorsulfonyl)oxaziridines
- Creators
- Diana M PogatchnikDavid F Wiemer
- Resource Type
- Journal article
- Publication Details
- Tetrahedron letters, Vol.38(20), pp.3495-3498
- Publisher
- Elsevier Ltd
- DOI
- 10.1016/S0040-4039(97)00705-3
- ISSN
- 0040-4039
- eISSN
- 1873-3581
- Language
- English
- Date published
- 1997
- Academic Unit
- Chemistry; Neuroscience and Pharmacology
- Record Identifier
- 9983985881202771
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