Journal article
Exploiting modularity in template-controlled synthesis: a new linear template to direct reactivity within discrete hydrogen-bonded molecular assemblies in the solid state
Chemical Communications, Vol.2001(23), pp.2462-2463
11/22/2001
DOI: 10.1039/b106584j
PMID: 12240015
Abstract
Co-crystallization of 1,8-naphthalenedicarboxylic acid (1,8-nap) with
trans
-1,2-bis(
n
-pyridyl)ethylene (
n,n
′-bpe) (
n
= 2 or 4) yields a discrete four-component molecular assembly, 2(
n,n
′-bpe)·2(1,8-nap)
1
, that is held together by four O-H N hydrogen bonds where the dicarboxylic acid, serving as a linear template, directs alignment of olefins in the solid state for [2 + 2] photoreaction.
Details
- Title: Subtitle
- Exploiting modularity in template-controlled synthesis: a new linear template to direct reactivity within discrete hydrogen-bonded molecular assemblies in the solid state
- Creators
- Giannis S PapaefstathiouAlex J KippLeonard R MacGillivray
- Resource Type
- Journal article
- Publication Details
- Chemical Communications, Vol.2001(23), pp.2462-2463
- DOI
- 10.1039/b106584j
- PMID
- 12240015
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Number of pages
- 2
- Date published
- 11/22/2001
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216595302771
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