Journal article
Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (η-C5Me4R)2Ta2(μ-Cl)4 (R = Me, Et) to a new μ-η1,η1-N2 complex and odd-electron organotrimetallic cluster
Chemical Communications, Vol.2005(43), pp.5444-5446
10/28/2005
DOI: 10.1039/b508148c
Abstract
(C 5 Me 5 R) 2 Ta 2 Cl 4 (d 2 -d 2 ) disproportionates under dinitrogen to [(C 5 Me 4 R)TaCl 2 ] 2 (μ-N 2 ) and the D 3h cluster cation (C 5 Me 4 R) 3 Ta 3 (μ-Cl) 6 + with anionic (C 5 Me 4 R)TaCl 4 − . The d 2 -d 2 organodimetallic (C 5 Me 4 R) 2 Ta 2 (μ-Cl) 4 disproportionates in toluene under N 2 to the new organodimetallic N 2 complex [(C 5 Me 4 R)TaCl 2 ] 2 (μ-N 2 ) and novel organotrimetallic cluster [(C 5 Me 4 R) 3 Ta 3 (μ-Cl) 6 ][(C 5 Me 4 R)TaCl 4 ].
Details
- Title: Subtitle
- Four-electron reduction of dinitrogen during solution disproportionation of the organodimetallic (η-C5Me4R)2Ta2(μ-Cl)4 (R = Me, Et) to a new μ-η1,η1-N2 complex and odd-electron organotrimetallic cluster
- Creators
- Ting-Yu LeeAlfred J WootenJeffrey J LuciDale C SwensonLouis Messerle
- Resource Type
- Journal article
- Publication Details
- Chemical Communications, Vol.2005(43), pp.5444-5446
- DOI
- 10.1039/b508148c
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Number of pages
- 3
- Date published
- 10/28/2005
- Academic Unit
- Chemistry; Radiology
- Record Identifier
- 9983985824802771
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