Journal article
Haloacetal Radical Cyclizations of α- and β-Hydroxyhydrazones
Organic letters, Vol.7(12), pp.2393-2396
06/09/2005
DOI: 10.1021/ol050663r
PMID: 15932206
Abstract
Haloacetal radical cyclizations of α- and β-hydroxyhydrazones provide a direct access to aminosugarlike compounds. Stereocontrol of this process is influenced by stereogenic centers of both the hydroxyhydrazone and the acetal. The outcomes are consistent with chair and twist transition states with the anomeric alkoxy group in pseudoaxial orientations.
Details
- Title: Subtitle
- Haloacetal Radical Cyclizations of α- and β-Hydroxyhydrazones
- Creators
- Gregory K FriestadGina M Fioroni
- Resource Type
- Journal article
- Publication Details
- Organic letters, Vol.7(12), pp.2393-2396
- Publisher
- American Chemical Society
- DOI
- 10.1021/ol050663r
- PMID
- 15932206
- ISSN
- 1523-7060
- eISSN
- 1523-7052
- Language
- English
- Date published
- 06/09/2005
- Academic Unit
- Chemistry
- Record Identifier
- 9983985975602771
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