Journal article
Halogen‐Bond‐Templated [2+2] Photodimerization in the Solid State: Directed Synthesis and Rare Self‐Inclusion of a Halogenated Product
Angewandte Chemie (International ed.), Vol.55(10), pp.3477-3480
03/01/2016
DOI: 10.1002/anie.201510912
PMID: 26836572
Abstract
A ditopic halogen‐bond acceptor organizes a diiodooctafluorostilbene for a [2+2] photodimerization reaction to take place between two stilbene molecules in the solid state. The resultant cyclobutane product is functionalized with halogen atoms and undergoes self‐assembly to form a channel‐type host–guest compound that exhibits a very rare form of self‐inclusion.
This way, please: A ditopic halogen‐bond acceptor organizes a halogenated stilbene for a stereoselective [2+2] photodimerization reaction to take place between two stilbenes in the solid state. The resultant halogen‐functionalized cyclobutane product self‐assembles to form a host–guest compound that exhibits a very rare form of self‐inclusion. Atom colors: C=gray; I=purple; N=blue; F=green.
Details
- Title: Subtitle
- Halogen‐Bond‐Templated [2+2] Photodimerization in the Solid State: Directed Synthesis and Rare Self‐Inclusion of a Halogenated Product
- Creators
- Michael A Sinnwell - University of IowaLeonard R MacGillivray - University of Iowa
- Resource Type
- Journal article
- Publication Details
- Angewandte Chemie (International ed.), Vol.55(10), pp.3477-3480
- DOI
- 10.1002/anie.201510912
- PMID
- 26836572
- NLM abbreviation
- Angew Chem Int Ed Engl
- ISSN
- 1433-7851
- eISSN
- 1521-3773
- Number of pages
- 4
- Grant note
- National Science Foundation (LRM DMR-1408834)
- Language
- English
- Date published
- 03/01/2016
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216672702771
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