Logo image
IRO Home Research units Researcher Profiles
Sign in
He I photoelectron spectra and gas-phase electronic structures of end-functionalized [3]- and [5]-ladderanes
Journal article

He I photoelectron spectra and gas-phase electronic structures of end-functionalized [3]- and [5]-ladderanes

Tomislav Friscić, Leo Klasinc, Branka Kovac and Leonard R Macgillivray
The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, Vol.112(7), pp.1493-1496
02/21/2008
DOI: 10.1021/jp072330c
PMID: 18225866

View Online

Abstract

[3]- and [5]-ladderanes obtained by way of template-controlled syntheses conducted in the organic solid state have been characterized via He I photoelectron (PE) spectroscopy. The results provide a first correlation with X-ray crystallographic structure data and establish the reliability of quantum chemical DFT (B3LYP/6-31G*) and ab initio HF calculations in predicting geometrical and electronic structures of molecular ladder frameworks.
Computer Simulation Cyclobutanes - chemistry Electrons Models, Chemical Molecular Structure Photochemistry Pyridines - chemical synthesis Pyridines - chemistry Pyridines - radiation effects Quantum Theory Reproducibility of Results Spectrum Analysis - methods Temperature Ultraviolet Rays

Details

Metrics

Logo image