Journal article
Heteroditopic Rebek's Imide Directs the Reactivity of Homoditopic Olefins within Desolvated Quaternary Assemblies in the Solid State
Angewandte Chemie (International ed.), Vol.45(4), pp.646-650
01/16/2006
DOI: 10.1002/anie.200502294
PMID: 16365834
Abstract
(Figure Presented) A rare single crystal to single crystal transformation leads to a [2+2] photodimerization of homoditopic olefins (trans-1,2-bis(4- pyridyl)ethylene) assembled and preorganized within hydrogen-bonded quaternary complexes by using Rebek's imide. In this way a rctt-tetrakis(4-pyridyl) cyclobutane (see picture) was obtained stereospecifically in up to 100% yield.
Details
- Title: Subtitle
- Heteroditopic Rebek's Imide Directs the Reactivity of Homoditopic Olefins within Desolvated Quaternary Assemblies in the Solid State
- Creators
- Dushyant B Varshney - Department of Chemistry, University of Iowa, Iowa City, IA 52242-1294, USA, Fax: (+1) 319-335-1270Xiuchun Gao - Department of Chemistry, University of Iowa, Iowa City, IA 52242-1294, USA, Fax: (+1) 319-335-1270Tomislav Friščić - Department of Chemistry, University of Iowa, Iowa City, IA 52242-1294, USA, Fax: (+1) 319-335-1270Leonard R MacGillivray - Department of Chemistry, University of Iowa, Iowa City, IA 52242-1294, USA, Fax: (+1) 319-335-1270
- Resource Type
- Journal article
- Publication Details
- Angewandte Chemie (International ed.), Vol.45(4), pp.646-650
- Publisher
- WILEY-VCH Verlag
- DOI
- 10.1002/anie.200502294
- PMID
- 16365834
- ISSN
- 1433-7851
- eISSN
- 1521-3773
- Number of pages
- 5
- Language
- English
- Date published
- 01/16/2006
- Academic Unit
- Pharmaceutical Sciences and Experimental Therapeutics; Chemistry
- Record Identifier
- 9984216676402771
Metrics
31 Record Views