Journal article
Homoleptic uranium and lanthanide phosphinodiboranates
Chemical communications (Cambridge, England), Vol.54(44), pp.5602-5605
2018
DOI: 10.1039/C8CC02862A
PMID: 29767205
Abstract
Here we report a new class of homoleptic f-element borohydride complexes called phosphinodiboranates. Treating UI3(1,4-dioxane)1.5, NdI3, or ErI3, with three equiv. of K(H3BPtBu2BH3) in Et2O yielded M2(H3BPtBu2BH3)6, where M = U, Nd, and Er. All three complexes form solid-state dimers, but exist as mixtures of monomers and dimers in solution.
Details
- Title: Subtitle
- Homoleptic uranium and lanthanide phosphinodiboranates
- Creators
- Anastasia V Blake - Department of Chemistry, The University of Iowa, Iowa City, USATaylor V Fetrow - Department of Chemistry, The University of Iowa, Iowa City, USAZachary J Theiler - Department of Chemistry, The University of Iowa, Iowa City, USABess Vlaisavljevich - Department of Chemistry, University of South Dakota, Vermillion, USAScott R Daly - Department of Chemistry, The University of Iowa, Iowa City, USA
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.54(44), pp.5602-5605
- DOI
- 10.1039/C8CC02862A
- PMID
- 29767205
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry
- Grant note
- DOI: 10.13039/100005187, name: U.S. Nuclear Regulatory Commission; DOI: 10.13039/100006132, name: Office of Science
- Language
- English
- Date published
- 2018
- Academic Unit
- Chemistry
- Record Identifier
- 9984216612402771
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