Journal article
Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour
Chemical communications (Cambridge, England), Vol.54(77), pp.10828-10831
2018
DOI: 10.1039/C8CC05240A
PMID: 30137085
Abstract
Physical properties of actinyl materials are influenced by the presence of oxo functional groups. Herein, we report large thermal expansion coefficients for a uranyl metal organic nanotube that switch from positive to negative upon dehydration. Different behaviour is observed in the neptunyl system due to variations in the oxo interactions.
Details
- Title: Subtitle
- Impacts of oxo interactions within actinyl metal organic materials: highlight on thermal expansion behaviour
- Creators
- Maurice K Payne - Department of Chemistry, University of Iowa, Iowa City, USAMikaela M Pyrch - Department of Chemistry, University of Iowa, Iowa City, USAMatthew Jubinsky - Department of Chemistry, University of Iowa, Iowa City, USAMadeline C Basile - Department of Chemistry, University of Iowa, Iowa City, USATori Z Forbes - Department of Chemistry, University of Iowa, Iowa City, USA
- Resource Type
- Journal article
- Publication Details
- Chemical communications (Cambridge, England), Vol.54(77), pp.10828-10831
- DOI
- 10.1039/C8CC05240A
- PMID
- 30137085
- NLM abbreviation
- Chem Commun (Camb)
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Publisher
- Royal Society of Chemistry
- Grant note
- DOI: 10.13039/100000078, name: Division of Materials Research, award: DMR1252831; DOI: 10.13039/100000015, name: U.S. Department of Energy, award: DE-SC0013980
- Language
- English
- Date published
- 2018
- Academic Unit
- Civil and Environmental Engineering; Chemistry
- Record Identifier
- 9983985970902771
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