Journal article
In an ionic liquid, high local friction is determined by the proximity to the charge network
The Journal of chemical physics, Vol.149(14), pp.144503-144503
10/14/2018
DOI: 10.1063/1.5045675
PMID: 30316258
Abstract
Structural heterogeneity in Ionic Liquids (ILs) is to a large extent defined by nanoscale apolar pockets that act as spacers between strings of positive and negative charges that alternate. In contrast to this, recent work from our group and that of others appear to indicate that dynamic, energetic, and mechanical heterogeneities are governed by the charged part of the liquid. In this article, we study the dynamics of methane, a small apolar solute, in the family of ILs 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ( /NTf ), with n = 2, 4, 8 at temperatures that make the viscosity for each liquid similar and around 8 cP. We do this in an attempt to equalize the effect of the solvent on the dynamics of the solute. In all cases, we find that solute proximity to charge-enhanced regions coincides with translationally caged regimes (high local friction) whereas the opposite is true in charge-depleted regions. In a way, these ILs behave like a liquid within a liquid where the charge network is the high friction component.
Details
- Title: Subtitle
- In an ionic liquid, high local friction is determined by the proximity to the charge network
- Creators
- Juan C Araque - School of Engineering, Benedictine College, Atchison, Kansas 66002, USAClaudio J Margulis - Department of Chemistry, University of Iowa, Iowa City, Iowa 52242, USA
- Resource Type
- Journal article
- Publication Details
- The Journal of chemical physics, Vol.149(14), pp.144503-144503
- Publisher
- United States
- DOI
- 10.1063/1.5045675
- PMID
- 30316258
- ISSN
- 1089-7690
- eISSN
- 1089-7690
- Grant note
- DOI: 10.13039/100000165, name: Division of Chemistry, award: 1664832
- Language
- English
- Date published
- 10/14/2018
- Academic Unit
- Chemistry
- Record Identifier
- 9983985933402771
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