Journal article
Infrared spectroscopic determination of methyl-chlorosilanes from the direct process reaction
Analytica chimica acta, Vol.222(1), pp.221-234
1989
DOI: 10.1016/S0003-2670(00)81897-8
Abstract
Infrared spectroscopy was used to determine the distribution of products from a flow reactor. Gas-phase methylchlorosilanes, which were formed in the copper-catalyzed reaction of methyl chloride with silicon, flowed through a gas cell used for the infrared measurements. The silanes could be determined simultaneously at pressures of 1–100 Torr in the presence of methyl chloride at atmospheric pressure. The calculated results were similar to those obtained by standard gas chromatographic techniques; however, the infrared method required only 15 s for data collection.
Details
- Title: Subtitle
- Infrared spectroscopic determination of methyl-chlorosilanes from the direct process reaction
- Creators
- H.Bruce FriedrichDavid M SevenichLee D Gasper-GalvinDavid G Rethwisch
- Resource Type
- Journal article
- Publication Details
- Analytica chimica acta, Vol.222(1), pp.221-234
- Publisher
- Elsevier B.V
- DOI
- 10.1016/S0003-2670(00)81897-8
- ISSN
- 0003-2670
- eISSN
- 1873-4324
- Language
- English
- Date published
- 1989
- Academic Unit
- Chemical and Biochemical Engineering; Chemistry
- Record Identifier
- 9984004093102771
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